Solvent Extraction and β-Diketones

Cytotoxicity of ruthenocene-containing β-diketones.

BACKGROUND Ferrocene-containing β-diketones and cisplatin, [(NH(3))(2)PtCl(2)], possess strong antineoplastic activity. No information is available regarding the anticancer activity of the corresponding ruthenocene complexes. This study examined the cytotoxicity of stable ruthenocene-containing β-diketones. The results were related to the cytotoxicity of cisplatin and the ease of ruthenium elec...

Synthesis of (E)-2-Styrylchromones and Flavones by Base-Catalyzed Cyclodehydration of the Appropriate β-Diketones Using Water as Solvent.

A low cost, safe, clean and environmentally benign base-catalyzed cyclodehydration of appropriate β-diketones affording (E)-2-styrylchromones and flavones in good yields is disclosed. Water was used as solvent and the reactions were heated using classical and microwave heating methods, under open and closed vessel conditions. β-Diketones having electron-donating and withdrawing substituents wer...

A Study for Extraction Kinetics of Β-Carotene from Oven Dried Carrot by Solvent Extraction

The main aim of this work was to study the kinetics of the extraction of β-carotene by solvent (ethanol) extraction from carrots dried at 50oC in an oven. The moisture content after drying was 11±1.5% (dry weight basis). Extraction time was 5 hours and extraction process was carried out at 30oC. The ratio of Carrot (gm): ethanol (ml) of 1:60 was maintained throughout the extraction process. The...

Arylazo derivatives of some fluorinated β-diketones and their metal complexes

Phenylazo and benzothiazolylazo derivatives of trifluoroacetylacetone andhexafluoroacetylacetone have been synthesized and characterized. Analytical and spectral datarevealed the existence of phenylazo derivatives in the intramolecularly hydrogen-bonded ketohydrazoneform while the benzothiazolylazo derivatives in the azo-enol form. The monobasicbidentate coordination of the phenylazo derivative...

Magnetic solvent extraction